Study on the storage stability of ceramic ink
Anjeka Experimental Report
Study on the storage stability of ceramic ink
Experimental project: Study on the storage stability of ceramic ink
Experimental category: Dispersant, anti settling agent testing
Experimenter: Product Application Engineer Xinzhong Zhai
Abstract:Ceramic inks were prepared using Anjikang dispersants 6042A and 6042B, anti-settling agents 4311, 4360, 6701, 972, and bentonite. The stability of the ceramic inks was evaluated by measuring the particle size, viscosity, centrifugal sedimentation rate, and sedimentation rate after thermal storage, as well as the hard settling rate. The experimental results indicate that the white oil-based ceramic ink prepared with Anjeka 6042B dispersant exhibits the best storage stability.
Keywords: dispersant, anti settling agent, particle size, viscosity, centrifugal precipitation rate1.
1.Objective
Ceramic inks were prepared using different formulations incorporating Anjeka dispersants 6042A and 6042B, anti-settling agents 4311, 4360, 6701, 972, and bentonite. The stability of the ceramic inks prepared with different formulations was investigated by evaluating particle size, viscosity, centrifugal sedimentation rate, as well as sedimentation rate and hard settling rate after thermal storage.
2. Experimental Protocol
Reagents:
Ceramic colorant (encapsulated red, Guose), dispersants Anjeka 6042A and Anjeka 6042B, anti-settling agents Anjeka 4311, Anjeka 4360, Anjeka 6701, 972, bentonite, white oil, cocoate, isopropyl laurate, ceramic pigment, and Mirui ceramic ink sample.
Instruments:
Centrifuge (Model 80-2B, Jiangsu Jinyi Instrument Technology Co., Ltd.), nanoparticle size analyzer (Model BeNano 90, Dandong Bettersize Instruments Co., Ltd.), oscillating disperser, rotational digital viscometer, ultrasonic disperser, oven.
Preparation of Ceramic Ink
White oil No. 10, cocoate, and dispersant were mixed in a certain proportion until homogeneous. The ceramic colorant was then added and mixed thoroughly. Zirconia beads (0.3 mm diameter) in an amount three times the mass of the slurry were added, and the mixture was placed in an oscillating disperser for dispersion.
Thermal Storage
The inks were stored in an oven at 50°C for 72 hours.
Testing Methods
Particle Size Measurement of Ceramic Colorant in Ink:
The ground slurry was diluted 10,000 times with white oil. The particle size of the colorant in the diluted ink was measured using a nanoparticle size analyzer.
Centrifugal Sedimentation Rate:
The inks were centrifuged at 3000 rpm for either 5 minutes or 10 minutes as specified.
Viscosity:
The viscosity of the inks was measured at 15°C using a rotational viscometer.
3. Experimental Formulations and Methods
3.1 Effect of Different Dispersants and Dosages on Centrifugal Sedimentation Rate
Table 1. Experimental Formulations for Different Dispersants and Dosages
Raw Material
1#
2#
3#
4#
5#
6#
Supplier
White Oil
42.5
43.35
44.2
42.5
43.35
44.2
Guose
Cocoate
7.5
7.65
7.8
7.5
7.65
7.8
Mirui
Dispersant 6042A
5
4
3
Anjeka
Dispersant 6042B
5
4
3
Anjeka
Encapsulated Red
45
45
45
45
45
45
Guose
3.1.1 Experimental Results and Discussion
After 8 hours of oscillating grinding, the particle size, viscosity, and centrifugal sedimentation rate were measured. The results are shown in Table 3.
Table 3. Particle Size, Viscosity, and Centrifugal Sedimentation Rate
1#
2#
3#
4#
5#
6#
Z-Average Particle Size(nm)
225.54
369.99
275.08
295.26
273.09
292.15
Viscosity(mpa.s)
291.9
551. 1
4340
52.64
421. 1
6076
Centrifugal Sedimentation Rate%(5min)
13. 12
13.48
21.30
5.36
12.39
21.36
Centrifugal Sedimentation Rate%(10min)
17. 11
24.18
32.44
7.69
17.29
26.28